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Achieving the Ag(001)-supported synthesis of heptacene from two related reactants reveals the effect of the presence of Br atoms on the reaction process. The properties of reactants, intermediates and end-products are further characterized by scanning tunneling microscopy and spectroscopy.

Graphical abstract: On-surface synthesis of heptacene on Ag(001) from brominated and non-brominated tetrahydroheptacene precursors

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