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Issue 55, 2018
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3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules

Odile Gavat,a  Thi Minh Nguyet Trinh,b  Emilie Moulin,a  Thomas Ellis,a  Mounir Maaloum,a  Eric Buhler,c  Guillaume Fleith,a  Jean-François Nierengarten*b  and  Nicolas Giuseppone*a 
Author affiliations

* Corresponding authors

a SAMS Research Group, Institut Charles Sadron, CNRS, University of Strasbourg, 23 rue du Loess, 67034 Strasbourg Cedex 2, BP 84087, France
E-mail: giuseppone@unistra.fr
Web: http://sams.ics-cnrs.unistra.fr/

b Laboratoire de Chimie des Matériaux Moléculaires, Université de Strasbourg et CNRS (LIMA – UMR 7042), Ecole Européenne de Chimie, Matériaux et Polymères (ECPM), 25 rue Becquerel, 67087 Strasbourg Cedex 2, France
E-mail: nierengarten@unistra.fr

c Matière et Systèmes Complexes (MSC) Laboratory, UMR CNRS 7057, Sorbonne Paris Cité, University of Paris Diderot-Paris VII, 75205 Paris Cedex 13, France

Abstract

A clickable fullerene hexa-adduct scaffold has been functionalized with twelve triarylamine subunits. The light-triggered self-assembly of this molecular unit leads to 3D honeycomb-like structures with inner pores of around 10 nm diameter. Multiple grafting of triarylamine subunits onto a hard-core C60 unit increases the dimensionality of the self-assembly process by reticulating the 1D nanowires typically obtained from the supramolecular polymerization of triarylamine monomers.

Graphical abstract: 3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules

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Publication details

The article was received on 22 May 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC04079F
Citation: Chem. Commun., 2018,54, 7657-7660
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    3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules

    O. Gavat, T. M. Nguyet Trinh, E. Moulin, T. Ellis, M. Maaloum, E. Buhler, G. Fleith, J. Nierengarten and N. Giuseppone, Chem. Commun., 2018, 54, 7657
    DOI: 10.1039/C8CC04079F

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