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Issue 55, 2018
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Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

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Abstract

IMes-derived thioureas in which the imidazolyl ring is directly substituted by one or two dimethylamino groups are redox-active, exhibiting one and two oxidized states, respectively. The structure, stability, and electronics of the oxidized species are investigated, emphasizing the decisive role of the amino substituents.

Graphical abstract: Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

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Publication details

The article was received on 16 May 2018, accepted on 15 Jun 2018 and first published on 15 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03934H
Citation: Chem. Commun., 2018,54, 7653-7656
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    Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

    M. Ruamps, S. Bastin, L. Rechignat, A. Sournia-Saquet, D. A. Valyaev, J. Mouesca, N. Lugan, V. Maurel and V. César, Chem. Commun., 2018, 54, 7653
    DOI: 10.1039/C8CC03934H

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