Issue 55, 2018
From the journal:

Chemical Communications

Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes†

Mirko Ruamps,a   Stéphanie Bastin, ORCID logo a   Lionel Rechignat,a   Alix Sournia-Saquet,a   Dmitry A. Valyaev, ORCID logo a   Jean-Marie Mouesca,b   Noël Lugan, ORCID logo a   Vincent Maurel*b  and  Vincent César ORCID logo *a  

* Corresponding authors

a LCC-CNRS, Université de Toulouse, INPT, UPS, 205 route de Narbonne, 31077 Toulouse cedex 4, France
E-mail: vincent.cesar@lcc-toulouse.fr

b Université Grenoble Alpes, CEA, CNRS, INAC, SyMMES, F-38000 Grenoble, France
E-mail: vincent.maurel@cea.fr

Abstract

IMes-derived thioureas in which the imidazolyl ring is directly substituted by one or two dimethylamino groups are redox-active, exhibiting one and two oxidized states, respectively. The structure, stability, and electronics of the oxidized species are investigated, emphasizing the decisive role of the amino substituents.

Graphical abstract: Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/C8CC03934H
Article type
Communication
Submitted
16 May 2018
Accepted
15 Jun 2018
First published
15 Jun 2018

Chem. Commun., 2018,54, 7653-7656

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Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

M. Ruamps, S. Bastin, L. Rechignat, A. Sournia-Saquet, D. A. Valyaev, J. Mouesca, N. Lugan, V. Maurel and V. César, Chem. Commun., 2018, 54, 7653 DOI: 10.1039/C8CC03934H

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