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Issue 91, 2018
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Exploring the electronic structure and speciation of aqueous and colloidal Pu with high energy resolution XANES and computations

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Abstract

Pu L3 HR-XANES and FEFF9 computations provide evidence for band-like 6d states in colloidal Pu contrasting to narrow 6d states in molecular Pu(IV). Pu L3 HR-XANES is valuable for bond length estimation in plutonyl, whereas Pu M5 HR-XANES is an advanced tool for analysing Pu redox states and 5f unoccupied density of states.

Graphical abstract: Exploring the electronic structure and speciation of aqueous and colloidal Pu with high energy resolution XANES and computations

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Article information


Submitted
24 Aug 2018
Accepted
24 Oct 2018
First published
29 Oct 2018

Chem. Commun., 2018,54, 12824-12827
Article type
Communication

Exploring the electronic structure and speciation of aqueous and colloidal Pu with high energy resolution XANES and computations

T. Vitova, I. Pidchenko, D. Fellhauer, T. Pruessmann, S. Bahl, K. Dardenne, T. Yokosawa, B. Schimmelpfennig, M. Altmaier, M. Denecke, J. Rothe and H. Geckeis, Chem. Commun., 2018, 54, 12824
DOI: 10.1039/C8CC06889E

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