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Issue 77, 2018
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Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

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Abstract

The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22− (PyCp22− = [2,6-(CH2C5H3)2C5H3N]2−) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce–Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy–Fe bonded species.

Graphical abstract: Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

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Supplementary files

Article information


Submitted
02 Jul 2018
Accepted
04 Sep 2018
First published
04 Sep 2018

Chem. Commun., 2018,54, 10893-10896
Article type
Communication
Author version available

Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

C. P. Burns, X. Yang, S. Sung, J. D. Wofford, N. S. Bhuvanesh, M. B. Hall and M. Nippe, Chem. Commun., 2018, 54, 10893 DOI: 10.1039/C8CC05243C

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