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Issue 7, 2017
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Red-emitting AIEgen for luminescent solar concentrators

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This study reports for the first time the use of a red-emitting AIEgen, i.e. TPE-AC, for the realization of efficient luminescent solar concentrators (LSCs) based on poly(methyl methacrylate) (PMMA) and polycarbonate (PC) thin films (25 ± 5 μm). TPE-AC is an AIEgen with D–A features that absorbs visible light in the range between 400 and 550 nm and emits fluorescence peaked at 600–620 nm, with a maximum quantum yield (QY) of 50% when dispersed (0.1–1.5 wt%) in PMMA and PC matrices. QY and lifetime investigations demonstrated that fluorescence quenching occurred with varying the TPE-AC concentration, even if the optical features were still significant even at the highest fluorophore content. Study of the LSCs’ performances yielded worthy optical efficiencies of 6.7% for the TPE-AC/PC systems due to their superior light harvesting features and the compatibility of the AIEgen within the PC matrix.

Graphical abstract: Red-emitting AIEgen for luminescent solar concentrators

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Publication details

The article was received on 10 Jan 2017, accepted on 22 Feb 2017 and first published on 24 Feb 2017

Article type: Research Article
DOI: 10.1039/C7QM00008A
Mater. Chem. Front., 2017,1, 1406-1412

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    Red-emitting AIEgen for luminescent solar concentrators

    F. De Nisi, R. Francischello, A. Battisti, A. Panniello, E. Fanizza, M. Striccoli, X. Gu, N. L. C. Leung, B. Z. Tang and A. Pucci, Mater. Chem. Front., 2017, 1, 1406
    DOI: 10.1039/C7QM00008A

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