A novel alb metalloring organic framework with a {Ni12Gd24} cage exhibiting a significant magnetocaloric effect

Ya-Nan Feng; Chong-Bin Tian; Shao-Wu Du

doi:10.1039/C7DT02358H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A novel alb metalloring organic framework with a {Ni₁₂Gd₂₄} cage exhibiting a significant magnetocaloric effect†

Ya-Nan Feng,^ab Chong-Bin Tian*^a and Shao-Wu Du

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, P. R. China
E-mail: tianchongbin@fjirsm.ac.cn, swdu@fjirsm.ac.cn

^b College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou 350116, P. R. China

Abstract

With the aid of a bifunctional 6-mercaptonicotinic acid ligand, a novel {Ni₁₂Gd₂₄} cage-based (6, 12)-c alb–MROF that is assembled from a {Gd₄(OH)₄(COO)₆} trigonal-prism building unit and a {Ni₆S₁₂} hexagonal-prism molecular building block has been synthesized for the first time. It exhibits a large MCE value of 29.86 J kg⁻¹ K⁻¹ for ΔH = 8 T at 2 K.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7DT02358H
Article type: Communication
Submitted: 30 Jun 2017
Accepted: 21 Jul 2017
First published: 21 Jul 2017

Download Citation

Dalton Trans., 2017,46, 10210-10214

Permissions

Request permissions

A novel alb metalloring organic framework with a {Ni₁₂Gd₂₄} cage exhibiting a significant magnetocaloric effect

Y. Feng, C. Tian and S. Du, Dalton Trans., 2017, 46, 10210 DOI: 10.1039/C7DT02358H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions