A mild post-functionalization method, based on a copper(I) catalyzed azide–alkyne cycloaddition, was developed for the fragile [P2W15V3]9− (PWV). PWV was functionalized with an azide and used as a platform to attach various alkyne functionalized compounds.
S. Vanhaecht, T. Quanten and T. N. Parac-Vogt, Dalton Trans., 2017, 46, 10215 DOI: 10.1039/C7DT02450A
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