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Issue 2, 2017
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Functional polyoxometalates from solvothermal reactions of VOSO4 with tripodal alkoxides – a study on the reactivity of different “tris” derivatives

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Abstract

We report a study on the structure directing effects of functional groups and counterions. The aim was to find a facile and high yielding synthetic procedure to obtain polyoxometalate (POM) building blocks for post-functionalisation. Therefore, solvothermal reactions of VOSO4 with various tris(hydroxymethyl)methane derivatives in alkaline methanolic solutions were investigated. In doing so, new POM fragments were isolated and characterised. The binding modes of the functionalised tripodal alkoxides turned out to be surprisingly different.

Graphical abstract: Functional polyoxometalates from solvothermal reactions of VOSO4 with tripodal alkoxides – a study on the reactivity of different “tris” derivatives

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Publication details

The article was received on 19 Sep 2016, accepted on 08 Dec 2016 and first published on 08 Dec 2016


Article type: Paper
DOI: 10.1039/C6DT03638D
Dalton Trans., 2017,46, 509-516
  • Open access: Creative Commons BY-NC license
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    Functional polyoxometalates from solvothermal reactions of VOSO4 with tripodal alkoxides – a study on the reactivity of different “tris” derivatives

    O. Nachtigall, A. Hagenbach, J. Wiecko, D. Lentz, U. Abram and J. Spandl, Dalton Trans., 2017, 46, 509
    DOI: 10.1039/C6DT03638D

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