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Issue 79, 2017

The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

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Abstract

A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain an ammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread.

Graphical abstract: The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

Supplementary files

Article information


Submitted
22 Aug 2017
Accepted
12 Sep 2017
First published
12 Sep 2017

Chem. Commun., 2017,53, 10874-10877
Article type
Communication

The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

B. Riss-Yaw, C. Clavel, Ph. Laurent and F. Coutrot, Chem. Commun., 2017, 53, 10874 DOI: 10.1039/C7CC06598A

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