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Issue 53, 2017
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Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

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Abstract

The functionalization of a spherical Keplerate-type polyoxometalate {Mo72V30} with a cationic azobenzene surfactant has been achieved through ionic self-assembly. The photoisomerisation reaction of this complex, which emerges in a light-triggered aggregation–disaggregation process, has been followed by 1H NMR spectroscopy, dynamic light scattering, absorption spectroscopy and scanning electron microscopy analyses.

Graphical abstract: Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

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Article information


Submitted
09 Mar 2017
Accepted
10 Apr 2017
First published
10 Apr 2017

Chem. Commun., 2017,53, 7278-7281
Article type
Communication

Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

G. Markiewicz, D. Pakulski, A. Galanti, V. Patroniak, A. Ciesielski, A. R. Stefankiewicz and P. Samorì, Chem. Commun., 2017, 53, 7278
DOI: 10.1039/C7CC01805C

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