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Issue 1, 2017
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Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

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Abstract

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.

Graphical abstract: Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

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Article information


Submitted
18 Aug 2016
Accepted
29 Nov 2016
First published
29 Nov 2016

Chem. Commun., 2017,53, 130-133
Article type
Communication

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

J. D. Fuhr, M. W. van der Meijden, L. J. Cristina, L. M. Rodríguez, R. M. Kellogg, J. E. Gayone, H. Ascolani and M. Lingenfelder, Chem. Commun., 2017, 53, 130
DOI: 10.1039/C6CC06785A

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