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Issue 4, 2017
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Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

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Abstract

A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(II)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed via this methodology.

Graphical abstract: Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

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Supplementary files

Article information


Submitted
20 Dec 2016
Accepted
05 Jan 2017
First published
10 Jan 2017

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2017,8, 2588-2591
Article type
Edge Article

Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

P. Williamson, A. Galván and M. J. Gaunt, Chem. Sci., 2017, 8, 2588
DOI: 10.1039/C6SC05581H

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