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Issue 33, 2017
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Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages

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Abstract

Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties.

Graphical abstract: Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages

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Supplementary files

Article information


Submitted
16 Jun 2017
Accepted
21 Jun 2017
First published
21 Jun 2017

Dalton Trans., 2017,46, 10809-10813
Article type
Paper

Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages

N. Struch, F. Topić, K. Rissanen and A. Lützen, Dalton Trans., 2017, 46, 10809
DOI: 10.1039/C7DT02182H

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