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Abstract | Cited by

Photosensitizing and emission properties of P(V) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.

Graphical abstract: Tuning photochemical properties of phosphorus(v) porphyrin photosensitizers

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