Highly selective CO2vs. N2 adsorption in the cavity of a molecular coordination cage

Abstract

Two M₈L₁₂ cubic coordination cages, as desolvated crystalline powders, preferentially adsorb CO₂ over N₂ with ideal selectivity CO₂/N₂ constants of 49 and 30 at 298 K. A binding site for CO₂ is suggested by crystallographic location of CS₂ within the cage cavity at an electropositive hydrogen-bond donor site, potentially explaining the high CO₂/N₂ selectivity compared to other materials with this level of porosity.