Nanophotonic perovskite solar cell architecture with a three-dimensional TiO2 nanodendrite scaffold for light trapping and electron collection

Abstract

Nanophotonic perovskite solar cells have been fabricated by infiltrating methylammonium lead iodide (MAPbI₃) into the interstices of the quasi-single-crystalline TiO₂ nanodendrite (ND) array. The TiO₂ ND array in the active layer serves as not only the nanophotonic light trapping structure but also the electron transport medium for enhancing both light harvesting and electron collection to challenge the issue of short electron diffusion length in MAPbI₃-based solar cells. Finite difference time domain simulation results indicate that the ND in the MAPbI₃ matrix exhibits superior light trapping performance compared to the nanorod (NR), which can well explain the comparable light harvesting in the MAPbI₃–TiO₂ ND and the MAPbI₃–TiO₂ NR solar cells although the MAPbI₃ amount in the former is ∼10% less. Moreover, the branches developed from the trunks of the NDs will extract the photoelectrons from MAPbI₃ to reduce the electron transport length in the MAPbI₃ matrix. The higher internal quantum efficiencies, especially at longer wavelengths, confirm the enhanced electron collection in the MAPbI₃–TiO₂ ND solar cell. Compared to the MAPbI₃–TiO₂ NR solar cell, the 22% and 25% enhancements in the average J_sc and PCE are respectively attained in the MAPbI₃–TiO₂ ND solar cells.