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Issue 9, 2016
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Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

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Abstract

Benzylamine has been applied as an arene source in C–H activation and coupling with different types of diazo compounds, leading to the synthesis of fused isoquinolines. This occurs via a mild synergistic rhodium- and copper-catalyzed process. Moreover, ecofriendly O2 has been used as a terminal oxidant with high efficiency.

Graphical abstract: Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

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Article information


Submitted
22 Jun 2016
Accepted
22 Jul 2016
First published
26 Jul 2016

Org. Chem. Front., 2016,3, 1159-1162
Article type
Research Article

Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

Q. Wang and X. Li, Org. Chem. Front., 2016, 3, 1159
DOI: 10.1039/C6QO00287K

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