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Issue 10, 2016
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Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

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Abstract

Reaction-pathway control of 2-lithio-2′-silylbiphenyls was accomplished in flow microreactor systems. Effective switching between the intermolecular reaction with an electrophile and the intramolecular reaction was performed at will by choosing an appropriate residence time and temperature region.

Graphical abstract: Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

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Article information


Submitted
09 Jun 2016
Accepted
25 Jul 2016
First published
26 Jul 2016

Org. Chem. Front., 2016,3, 1250-1253
Article type
Research Article

Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls

A. Nagaki, S. Kim, N. Miuchi, H. Yamashita, K. Hirose and J. Yoshida, Org. Chem. Front., 2016, 3, 1250
DOI: 10.1039/C6QO00257A

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