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Issue 10, 2016
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Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands

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Abstract

A novel type of binaphthyl-based phosphoramidite-thioether ligand has been developed and successfully applied to Pd-catalysed asymmetric C-3 allylic alkylation of indoles, giving the desired products with up to 99% yield and 98% ee.

Graphical abstract: Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands

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Article information


Submitted
27 May 2016
Accepted
27 Jun 2016
First published
28 Jun 2016

Org. Chem. Front., 2016,3, 1246-1249
Article type
Research Article

Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands

B. Feng, X. Pu, Z. Liu, W. Xiao and J. Chen, Org. Chem. Front., 2016, 3, 1246
DOI: 10.1039/C6QO00227G

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