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Issue 4, 2016
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Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins

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Abstract

We reported herein a simple and efficient visible-light promoted intermolecular haloamination and haloetherification of alkenes using N-halosaccharin as the halogen and nitrogen/oxygen source (halo = Br, Cl). The reaction can be applied to a very broad range of alkenes to generate haloamines and haloethers with high isolated yields. With DBU as the base, metal-free C–H amination of aryl olefins has also been achieved with good yields.

Graphical abstract: Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins

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Article information


Submitted
18 Dec 2015
Accepted
22 Jan 2016
First published
26 Jan 2016

Org. Chem. Front., 2016,3, 447-452
Article type
Research Article

Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins

L. Song, S. Luo and J. Cheng, Org. Chem. Front., 2016, 3, 447
DOI: 10.1039/C5QO00432B

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