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Using copper complexes with an axially chiral bipyridine ligand C4-ACBP as the catalyst, an enantioselective functionalization of indoles with diazo compounds was developed with up to 95% ee. This protocol paves the way for further applications of these ligands.

Graphical abstract: Copper-catalyzed enantioselective C–H functionalization of indoles with an axially chiral bipyridine ligand

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