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Issue 26, 2016
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UGT74B1 from Arabidopsis thaliana as a versatile biocatalyst for the synthesis of desulfoglycosinolates

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Abstract

Thioglycosides, even if rare in Nature, have gained increased interest for their biological properties. Chemical syntheses of this class of compounds have been largely studied but little has been reported on their biosynthesis. Herein, combining experiments from the different fields of enzymology, bioorganic chemistry and molecular modeling, we wish to demonstrate the versatility of the glucosyltransferase UGT74B1 and its synthetic potency for the preparation of a variety of natural and unnatural desulfoglycosinolates.

Graphical abstract: UGT74B1 from Arabidopsis thaliana as a versatile biocatalyst for the synthesis of desulfoglycosinolates

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Publication details

The article was received on 08 May 2016, accepted on 24 May 2016 and first published on 25 May 2016


Article type: Paper
DOI: 10.1039/C6OB01003B
Citation: Org. Biomol. Chem., 2016,14, 6252-6261

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    UGT74B1 from Arabidopsis thaliana as a versatile biocatalyst for the synthesis of desulfoglycosinolates

    S. Marroun, S. Montaut, S. Marquès, P. Lafite, G. Coadou, P. Rollin, G. Jousset, M. Schuler, A. Tatibouët, H. Oulyadi and R. Daniellou, Org. Biomol. Chem., 2016, 14, 6252
    DOI: 10.1039/C6OB01003B

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