Issue 4, 2016
From the journal:

Dalton Transactions

Preparation and reactivity of a Ru(0) phosphino–carbene complex†

Eliar Mosaferi,a   Li Pan,a   Tongen Wang,a   Yunshan Sun,a   Conor Pranckeviciusa  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, 80 St. George Street, University of Toronto, Toronto, Ontario, Canada M5S 3H6
E-mail: dstephan@chem.utoronto.ca

Abstract

The reaction of the phosphino–carbene MeNC3H2NPtBu2 with RuHCl(CO)(PPh3)3 is shown to give facile access to the Ru(0) species (MeNC3H2NPtBu2)Ru(CO)(PPh3)2 (1). This species undergoes oxidative addition of H2 and silanes to give (MeNC3H2NPtBu2)RuH2(CO)(PPh3)24, (MeNC3H2NPtBu2)Ru H(SiRPh2)(CO)(PPh3) (R = Ph 5, H 6) and (MeNC3H2NPtBu2) RuH(PhSi(SCH2CH2)2O)(CO)(PPh3) 7.

Graphical abstract: Preparation and reactivity of a Ru(0) phosphino–carbene complex

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Article information

DOI
https://doi.org/10.1039/C5DT04337A
Article type
Communication
Submitted
03 Nov 2015
Accepted
05 Jan 2016
First published
05 Jan 2016

Dalton Trans., 2016,45, 1354-1358

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Preparation and reactivity of a Ru(0) phosphino–carbene complex

E. Mosaferi, L. Pan, T. Wang, Y. Sun, C. Pranckevicius and D. W. Stephan, Dalton Trans., 2016, 45, 1354 DOI: 10.1039/C5DT04337A

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