Comproportionation reactions between MnCl2 and KMnO4 in the presence of arsonate or phosphonate ligands promote the cation-assisted assembly of high-nuclearity, wheel-shaped or toroidal {Mn8} (1) and {Mn24} (2) complexes; the closely corresponding reaction systems provide insights into the complexation behaviour of homologous phosphonate/arsonate ligand species.
T. O. Chimamkpam, R. Clérac, D. Mitcov, B. Twamley, M. Venkatesan and W. Schmitt, Dalton Trans., 2016, 45, 1349 DOI: 10.1039/C5DT04820F
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