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Issue 23, 2016
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Anion-templated 2D frameworks from hexahydroxytriphenylene

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Abstract

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4 was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3).

Graphical abstract: Anion-templated 2D frameworks from hexahydroxytriphenylene

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Article information


Submitted
03 Feb 2016
Accepted
27 Mar 2016
First published
06 Apr 2016

This article is Open Access

CrystEngComm, 2016,18, 4281-4284
Article type
Communication

Anion-templated 2D frameworks from hexahydroxytriphenylene

M. Morshedi, A. C. Willis and N. G. White, CrystEngComm, 2016, 18, 4281
DOI: 10.1039/C6CE00297H

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