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Issue 65, 2016
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Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation

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Abstract

Aminotroponiminates (atis) are shown to be redox-active ligands. Under strongly reducing conditions, the result of electron transfer can be controlled by the choice of the metal bound to the ati ligand. Either reversible electron transfer or a reductively induced dimerisation is observed. The latter reaction is (regio- and diastereo-) selective and chemically reversible.

Graphical abstract: Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation

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Article information


Submitted
13 Jul 2016
Accepted
20 Jul 2016
First published
20 Jul 2016

Chem. Commun., 2016,52, 10044-10047
Article type
Communication

Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation

C. Lichtenberg and I. Krummenacher, Chem. Commun., 2016, 52, 10044
DOI: 10.1039/C6CC05762D

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