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Issue 40, 2016
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A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

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Abstract

The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.

Graphical abstract: A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

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Article information


Submitted
21 Dec 2015
Accepted
19 Apr 2016
First published
19 Apr 2016

Chem. Commun., 2016,52, 6677-6680
Article type
Communication

A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

D. García, L. Rodríguez-Pérez, M. A. Herranz, D. Peña, E. Guitián, S. Bailey, Q. Al-Galiby, M. Noori, C. J. Lambert, D. Pérez and N. Martín, Chem. Commun., 2016, 52, 6677
DOI: 10.1039/C5CC10462A

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