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Issue 13, 2016
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An azine-linked hexaphenylbenzene based covalent organic framework

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Abstract

In this communication, we report an azine linked covalent organic framework based on a six-fold symmetric hexphenylbenzene (HEX) monomer functionalized with aldehyde groups. HEX-COF 1 has an average pore size of 1 nm, a surface area in excess of 1200 m2 g−1 and shows excellent sorption capability for carbon dioxide (20 wt%) and methane (2.3 wt%) at 273 K and 1 atm.

Graphical abstract: An azine-linked hexaphenylbenzene based covalent organic framework

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Supplementary files

Article information


Submitted
18 Dec 2015
Accepted
10 Jan 2016
First published
11 Jan 2016

Chem. Commun., 2016,52, 2843-2845
Article type
Communication

An azine-linked hexaphenylbenzene based covalent organic framework

S. B. Alahakoon, C. M. Thompson, A. X. Nguyen, G. Occhialini, G. T. McCandless and R. A. Smaldone, Chem. Commun., 2016, 52, 2843
DOI: 10.1039/C5CC10408D

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