Pure white-light and colour-tuning of Eu3+–Gd3+-containing metallopolymer

Zhao Zhang; Ya-Ni He; Lin Liu; Xing-Qiang Lü; Xun-Jin Zhu; Wai-Kwok Wong; Mei Pan; Cheng-Yong Su

doi:10.1039/C5CC09946C

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Pure white-light and colour-tuning of Eu³⁺–Gd³⁺-containing metallopolymer†

Zhao Zhang,^a Ya-Ni He,^a Lin Liu,^a Xing-Qiang Lü,*^a Xun-Jin Zhu,^b Wai-Kwok Wong,^b Mei Pan^c and Cheng-Yong Su

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* Corresponding authors

^a School of Chemical Engineering, Shaanxi Key Laboratory of Degradable Medical Material, Northwest University, Xi'an 710069, Shaanxi, P. R. China
E-mail: lvxq@nwu.edu.cn
Fax: +86-29-88302312
Tel: +86-29-88302312

^b Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, P. R. China

^c MOE Laboratory of Bioinoragnic and Synthetic Chemistry/KLGH EI of Environment and Energy Chemistry, School of Chemi and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, Guangdong, P. R. China

Abstract

Direct white-light (CIE coordinate of x = 0.333, y = 0.335, CCT of 5455 K and CRI of 82) with a high luminous efficiency (18.4%) was achieved in the first example of Eu³⁺–Gd³⁺-containing metallopolymer Poly(2-co-NVK-co-4), which also showed tunable purplish-blue to white to yellow-green photoluminescence.

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Article information

DOI: https://doi.org/10.1039/C5CC09946C
Article type: Communication
Submitted: 03 Dec 2015
Accepted: 29 Jan 2016
First published: 04 Feb 2016

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Chem. Commun., 2016,52, 3713-3716

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Pure white-light and colour-tuning of Eu³⁺–Gd³⁺-containing metallopolymer

Z. Zhang, Y. He, L. Liu, X. Lü, X. Zhu, W. Wong, M. Pan and C. Su, Chem. Commun., 2016, 52, 3713 DOI: 10.1039/C5CC09946C

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Chemical Communications