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Direct white-light (CIE coordinate of x = 0.333, y = 0.335, CCT of 5455 K and CRI of 82) with a high luminous efficiency (18.4%) was achieved in the first example of Eu3+–Gd3+-containing metallopolymer Poly(2-co-NVK-co-4), which also showed tunable purplish-blue to white to yellow-green photoluminescence.

Graphical abstract: Pure white-light and colour-tuning of Eu3+–Gd3+-containing metallopolymer

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