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Issue 14, 2016
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Gold(I) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides

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Abstract

The intermolecular reaction of allenamides with aldehydes is reported. The designed approach relies on gold(I) and organocatalysis for activating the allenamides and the aldehydes respectively. Conditions to achieve an enantioselective version of this intermolecular reaction are defined.

Graphical abstract: Gold(i) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides

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Publication details

The article was received on 17 Nov 2015, accepted on 08 Jan 2016 and first published on 08 Jan 2016


Article type: Communication
DOI: 10.1039/C5CC09529H
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Chem. Commun., 2016,52, 2905-2908

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    Gold(I) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides

    A. Ballesteros, P. Morán-Poladura and J. M. González, Chem. Commun., 2016, 52, 2905
    DOI: 10.1039/C5CC09529H

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