An amide-derived N,N,N-Ru(II) complex catalyzes the conversion of EtOH to 1-BuOH with high activity. Conversion to alcohol upgraded products exceeds 250 turnovers per hour (>50% conversion) with 0.1 mol% catalyst loading. In addition to high activity for ethanol upgrading, catalytic reactions can be set up under ambient conditions with no loss in activity.
K. T. Tseng, S. Lin, J. W. Kampf and N. K. Szymczak, Chem. Commun., 2016, 52, 2901 DOI: 10.1039/C5CC09913G
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