Issue 2, 2016
From the journal:

RSC Advances

A new magnesium-containing aluminophosphate with a zeolite-like structure†

Xuejiao Jiao,a   Yanyan Wang,a   Ying Mu,a   Yanjun Suna  and  Jiyang Li*a  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: lijiyang@jlu.edu.cn
Fax: +86-431-85168614

Abstract

A novel Mg-containing aluminophosphate |C4H12N2|[Mg2Al6(PO4)8(H2O)4] (JU96) has been hydrothermally synthesized using piperazine as a structure-directing agent. Its framework, constructed by the connection of AlO4/MgO4(H2O)2 polyhedra and PO4 tetrahedra, exhibits a new 4-connected zeolite-like topology with intersecting 8-ring channels. Such a framework contains unique [44·66·86] cages that are occupied by diprotonated piperazine cations. Study shows that the presence of Mg atoms and the pH value of the reaction gel have a vital effect on the formation of JU96.

Graphical abstract: A new magnesium-containing aluminophosphate with a zeolite-like structure

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Article information

DOI
https://doi.org/10.1039/C5RA22194C
Article type
Paper
Submitted
23 Oct 2015
Accepted
02 Dec 2015
First published
07 Dec 2015

RSC Adv., 2016,6, 1098-1102

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A new magnesium-containing aluminophosphate with a zeolite-like structure

X. Jiao, Y. Wang, Y. Mu, Y. Sun and J. Li, RSC Adv., 2016, 6, 1098 DOI: 10.1039/C5RA22194C

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