Jump to main content
Jump to site search

Issue 2, 2016
Previous Article Next Article

A new magnesium-containing aluminophosphate with a zeolite-like structure

Author affiliations

Abstract

A novel Mg-containing aluminophosphate |C4H12N2|[Mg2Al6(PO4)8(H2O)4] (JU96) has been hydrothermally synthesized using piperazine as a structure-directing agent. Its framework, constructed by the connection of AlO4/MgO4(H2O)2 polyhedra and PO4 tetrahedra, exhibits a new 4-connected zeolite-like topology with intersecting 8-ring channels. Such a framework contains unique [44·66·86] cages that are occupied by diprotonated piperazine cations. Study shows that the presence of Mg atoms and the pH value of the reaction gel have a vital effect on the formation of JU96.

Graphical abstract: A new magnesium-containing aluminophosphate with a zeolite-like structure

Back to tab navigation

Supplementary files

Publication details

The article was received on 23 Oct 2015, accepted on 02 Dec 2015 and first published on 07 Dec 2015


Article type: Paper
DOI: 10.1039/C5RA22194C
Author version
available:
Download author version (PDF)
RSC Adv., 2016,6, 1098-1102

  •   Request permissions

    A new magnesium-containing aluminophosphate with a zeolite-like structure

    X. Jiao, Y. Wang, Y. Mu, Y. Sun and J. Li, RSC Adv., 2016, 6, 1098
    DOI: 10.1039/C5RA22194C

Search articles by author

Spotlight

Advertisements