Metal-free reductive coupling of CO and CN bonds driven by visible light: use of perylene as a simple photoredox catalyst

Shusuke Okamoto; Keita Kojiyama; Hiroki Tsujioka; Atsushi Sudo

doi:10.1039/C6CC05867A

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Metal-free reductive coupling of CO and CN bonds driven by visible light: use of perylene as a simple photoredox catalyst†

Shusuke Okamoto,^a Keita Kojiyama,^a Hiroki Tsujioka^a and Atsushi Sudo*^a

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* Corresponding authors

^a Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 11-6 kowakae, Higashi Osaka, Osaka 577-8502, Japan
E-mail: asudo@apch.kindai.ac.jp

Abstract

Perylene, a simple polycyclic aromatic hydrocarbon, was used as a photoredox catalyst to enable the reductive coupling reaction of aromatic aldehydes, ketones, and an imine under visible-light irradiation using a white LED.

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Article information

DOI: https://doi.org/10.1039/C6CC05867A
Article type: Communication
Submitted: 16 Jul 2016
Accepted: 05 Aug 2016
First published: 05 Aug 2016

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Chem. Commun., 2016,52, 11339-11342

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Metal-free reductive coupling of CO and CN bonds driven by visible light: use of perylene as a simple photoredox catalyst

S. Okamoto, K. Kojiyama, H. Tsujioka and A. Sudo, Chem. Commun., 2016, 52, 11339 DOI: 10.1039/C6CC05867A

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Chemical Communications

Metal-free reductive coupling of CO and CN bonds driven by visible light: use of perylene as a simple photoredox catalyst†

Abstract

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Metal-free reductive coupling of CO and CN bonds driven by visible light: use of perylene as a simple photoredox catalyst

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