Multifaceted chelating μ-(η3:η3-antifacial)-(cis-C4R2H2) coordination motif in binuclear complexes

Cham-Chuen Liu; Michael C. W. Chan; Po-Kam Lo; Kai-Chung Lau; Shek-Man Yiu

doi:10.1039/C6CC05535D

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Multifaceted chelating μ-(η³:η³-antifacial)-(cis-C₄R₂H₂) coordination motif in binuclear complexes†

Cham-Chuen Liu,^a Michael C. W. Chan,

*^a Po-Kam Lo,^a Kai-Chung Lau*^a and Shek-Man Yiu^a

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* Corresponding authors

^a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China
E-mail: mcwchan@cityu.edu.hk, kaichung@cityu.edu.hk

Abstract

A novel μ-C₄R₂H₂ core structure (formed by an unprecedented regioselective, redox-neutral C(sp²)–C(sp²) coupling process) in binuclear group 4 complexes displays adaptable coordination and accommodates different metal sizes, and is sufficiently robust to promote interesting catalytic reactivity at the bimetallic centers.

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Article information

DOI: https://doi.org/10.1039/C6CC05535D
Article type: Communication
Submitted: 04 Jul 2016
Accepted: 03 Aug 2016
First published: 03 Aug 2016

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Chem. Commun., 2016,52, 11056-11059

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Multifaceted chelating μ-(η³:η³-antifacial)-(cis-C₄R₂H₂) coordination motif in binuclear complexes

C. Liu, M. C. W. Chan, P. Lo, K. Lau and S. Yiu, Chem. Commun., 2016, 52, 11056 DOI: 10.1039/C6CC05535D

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