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Issue 18, 2016
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Visible-light-induced water oxidation by a hybrid photocatalyst consisting of bismuth vanadate and copper(ii) meso-tetra(4-carboxyphenyl)porphyrin

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Abstract

Copper(II) meso-tetra(4-carboxyphenyl)porphyrin surface-modified monoclinic scheelite bismuth vanadate (CuTCPP/BiVO4) has been synthesized via a two-step route involving chemisorption of TCPP on BiVO4 and successive Cu(II) ion incorporation into the TCPP, and the surface modification drastically enhances the water oxidation to oxygen (O2) under visible-light irradiation (λ > 430 nm).

Graphical abstract: Visible-light-induced water oxidation by a hybrid photocatalyst consisting of bismuth vanadate and copper(ii) meso-tetra(4-carboxyphenyl)porphyrin

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Supplementary files

Article information


Submitted
05 Dec 2015
Accepted
01 Feb 2016
First published
01 Feb 2016

Chem. Commun., 2016,52, 3665-3668
Article type
Communication

Visible-light-induced water oxidation by a hybrid photocatalyst consisting of bismuth vanadate and copper(II) meso-tetra(4-carboxyphenyl)porphyrin

S. Nakashima, R. Negishi and H. Tada, Chem. Commun., 2016, 52, 3665
DOI: 10.1039/C5CC10014C

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