Efficient ceramic zeolite membranes for CO2/H2 separation

Abstract

Membranes are considered one of the most promising technologies for CO₂ separation from industrially important gas mixtures like synthesis gas or natural gas. In order for the membrane separation process to be efficient, membranes, in addition to being cost-effective, should be durable and possess high flux and sufficient selectivity. Current CO₂-selective membranes are low flux polymeric membranes with limited chemical and thermal stability. In the present work, robust and high flux ceramic MFI zeolite membranes were prepared and evaluated for separation of CO₂ from H₂, a process of great importance to synthesis gas processing, in a broad temperature range of 235–310 K and at an industrially relevant feed pressure of 9 bar. The observed membrane separation performance in terms of both selectivity and flux was superior to that previously reported for the state-of-the-art CO₂-selective zeolite and polymeric membranes. Our initial cost estimate of the membrane modules showed that the present membranes were economically viable. We also showed that the ceramic zeolite membrane separation system would be much more compact than a system relying on polymeric membranes. Our findings therefore suggest that the developed high flux ceramic zeolite membranes have great potential for selective, cost-effective and sustainable removal of CO₂ from synthesis gas.