An organocatalytic inverse-electron-demand Diels–Alder reaction of ketones with 1,3,5-triazine through enamine catalysis has been developed. This method could furnish 4,5-disubstituted pyrimidines in good yields and high levels of regioselectivities.
G. Yang, Q. Jia, L. Chen, Z. Du and J. Wang, RSC Adv., 2015, 5, 76759 DOI: 10.1039/C5RA16995J
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