Issue 120, 2015
From the journal:

RSC Advances

Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen†‡

L. Novkovic,a   M. Trmcic,a   M. Rodic, ORCID logo b   F. Bihelovic,c   M. Zlatar,d   R. Matovicd  and  R. N. Saicic*c  

* Corresponding authors

a Innovative Centre of the Faculty of Chemistry, University of Belgrade, Serbia

b Department of Chemistry, University of Novi Sad, Novi Sad, Serbia

c Faculty of Chemistry, University of Belgrade, Studentski trg 16, POB 51, 11158 Belgrade 118, Serbia
E-mail: rsaicic@chem.bg.ac.rs

d ICTM Center for Chemistry, Njegoseva 12, Belgrade, Serbia

Abstract

Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.

Graphical abstract: Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

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Article information

DOI
https://doi.org/10.1039/C5RA13476E
Article type
Paper
Submitted
09 Jul 2015
Accepted
12 Nov 2015
First published
13 Nov 2015
This article is Open Access
Creative Commons BY license

RSC Adv., 2015,5, 99577-99584

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Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

L. Novkovic, M. Trmcic, M. Rodic, F. Bihelovic, M. Zlatar, R. Matovic and R. N. Saicic, RSC Adv., 2015, 5, 99577 DOI: 10.1039/C5RA13476E

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