Issue 62, 2015
From the journal:

RSC Advances

Unexpected C[double bond, length as m-dash]N bond formation via NaI-catalyzed oxidative de-tetra-hydrogenative cross-couplings between N,N-dimethyl aniline and sulfamides†

Yang Zheng,a   Jincheng Mao,*ab   Jie Chen,a   Guangwei Rong,a   Defu Liu,a   Hong Yan,a   Yongjian Chia  and  Xinfang Xu*a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: xinfangxu@suda.edu.cn

b State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, P. R. China
E-mail: jcmao@suda.edu.cn

Abstract

A direct and convenient C[double bond, length as m-dash]N bond formation reaction was reported, which was a de-tetra-hydrogenative cross-coupling (DTCC) reaction between N,N-dimethyl aniline and sulfamide under transition-metal-free conditions, and to give sulfonyl amidine derivatives in moderate to high yields.

Graphical abstract: Unexpected C [[double bond, length as m-dash]] N bond formation via NaI-catalyzed oxidative de-tetra-hydrogenative cross-couplings between N,N-dimethyl aniline and sulfamides

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Article information

DOI
https://doi.org/10.1039/C5RA06773A
Article type
Communication
Submitted
15 Apr 2015
Accepted
01 Jun 2015
First published
01 Jun 2015

RSC Adv., 2015,5, 50113-50117

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Unexpected C[double bond, length as m-dash]N bond formation via NaI-catalyzed oxidative de-tetra-hydrogenative cross-couplings between N,N-dimethyl aniline and sulfamides

Y. Zheng, J. Mao, J. Chen, G. Rong, D. Liu, H. Yan, Y. Chi and X. Xu, RSC Adv., 2015, 5, 50113 DOI: 10.1039/C5RA06773A

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