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Issue 5, 2015
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An alkyne hydrosilylation–Hiyama coupling approach to highly functionalised 1,3-dienes

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Abstract

A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.

Graphical abstract: An alkyne hydrosilylation–Hiyama coupling approach to highly functionalised 1,3-dienes

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Article information


Submitted
02 Jan 2015
Accepted
12 Mar 2015
First published
17 Mar 2015

Org. Chem. Front., 2015,2, 510-514
Article type
Research Article
Author version available

An alkyne hydrosilylation–Hiyama coupling approach to highly functionalised 1,3-dienes

C. A. McAdam, M. G. McLaughlin and M. J. Cook, Org. Chem. Front., 2015, 2, 510
DOI: 10.1039/C5QO00002E

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