Issue 5, 2015
From the journal:

Organic Chemistry Frontiers

An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones†

Hai-Tao Zhu,*a   Ming-Jin Fan,a   De-Suo Yang,*a   Xiao-Ling Wang,a   Sen Ke,a   Chao-Yang Zhanga  and  Zheng-Hui Guan*b  

* Corresponding authors

a Shannxi Key Laboratory of Phytochemistry, Baoji University of Arts and Sciences, Baoji 721013, China
E-mail: 1888@bjwlxy.edu.cn

b Key Laboratory of Synthesis and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
E-mail: guanzhh@nwu.edu.cn

Abstract

A facile and efficient iodine-promoted Meyer–Schuster rearrangement of propargyl alcohols for the synthesis of α-iodo-α,β-unsaturated ketones is presented. The reaction is concisely conducted at ambient temperature and shows good functional group tolerance.

Graphical abstract: An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5QO00048C
Article type
Research Article
Submitted
06 Feb 2015
Accepted
10 Mar 2015
First published
13 Mar 2015

Org. Chem. Front., 2015,2, 506-509

Author version available

Download author version (PDF)

Permissions

Request permissions

An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

H. Zhu, M. Fan, D. Yang, X. Wang, S. Ke, C. Zhang and Z. Guan, Org. Chem. Front., 2015, 2, 506 DOI: 10.1039/C5QO00048C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements