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Gradient porous membranes were prepared from a poly(4-vinylpyridinium)-based poly(ionic liquid) together with carboxylic multi-acid compounds via electrostatic complexation. Their unique tuneable actuation kinetics in a humid environment as well as their intrinsic cell toxicity were studied.

Graphical abstract: Polyvinylpyridinium-type gradient porous membranes: synthesis, actuation and intrinsic cell growth inhibition

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