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Issue 17, 2015
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Pd-catalyzed enantioselective intramolecular α-arylation of α-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles

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Abstract

Catalytic synthesis of chiral spirocyclic ketones was accomplished via the Pd-catalyzed intramolecular α-arylation of α-substituted cyclic ketones. The obtained spirocyclic ketone could be converted into a bifunctional organocatalyst.

Graphical abstract: Pd-catalyzed enantioselective intramolecular α-arylation of α-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles

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Article information


Submitted
25 Feb 2015
Accepted
17 Mar 2015
First published
17 Mar 2015

Org. Biomol. Chem., 2015,13, 4837-4840
Article type
Communication
Author version available

Pd-catalyzed enantioselective intramolecular α-arylation of α-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles

L. Fan, S. Takizawa, Y. Takeuchi, K. Takenaka and H. Sasai, Org. Biomol. Chem., 2015, 13, 4837
DOI: 10.1039/C5OB00382B

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