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Issue 6, 2015
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Studies towards the synthesis of bielschowskysin. Construction of the highly functionalized bicyclo[3.2.0]heptane segment

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Abstract

A stereocontrolled approach for the construction of a highly functionalized bicyclo[3.2.0]heptane derivative embodying the bridged lactone present in the diterpene bielschowskysin is reported. The key step involves a stereoselective Cu(I)-catalyzed [2 + 2] photocycloaddition of a 1,6-diene embedded in a sugar derivative.

Graphical abstract: Studies towards the synthesis of bielschowskysin. Construction of the highly functionalized bicyclo[3.2.0]heptane segment

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Publication details

The article was received on 14 Oct 2014, accepted on 02 Dec 2014 and first published on 02 Dec 2014


Article type: Paper
DOI: 10.1039/C4OB02182G
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Org. Biomol. Chem., 2015,13, 1846-1859

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    Studies towards the synthesis of bielschowskysin. Construction of the highly functionalized bicyclo[3.2.0]heptane segment

    A. Jana, S. Mondal and S. Ghosh, Org. Biomol. Chem., 2015, 13, 1846
    DOI: 10.1039/C4OB02182G

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