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Issue 3, 2016
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Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

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Abstract

Herein we report a dinickel azacryptand complex that enables fast, selective, and tight CO2 binding from air. Exploiting the affinity of the cavitand towards azides, CO2 release was observed. Despite the stability of the azido complex, UV irradiation under atmospheric conditions proved to be a suitable pathway for N3 replacement by CO2.

Graphical abstract: Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

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Publication details

The article was received on 30 Oct 2015, accepted on 08 Dec 2015 and first published on 09 Dec 2015


Article type: Communication
DOI: 10.1039/C5DT04267D
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Dalton Trans., 2016,45, 904-907
  • Open access: Creative Commons BY license
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    Bimetallic nickel complexes for selective CO2 carbon capture and sequestration

    F. Möller, K. Merz, C. Herrmann and U.-P. Apfel, Dalton Trans., 2016, 45, 904
    DOI: 10.1039/C5DT04267D

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