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Issue 27, 2015
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Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

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Abstract

This Perspective provides an overview of the oxidative cyclization reactions of alkynes and imines with nickel(0) to give five-membered aza-nickelacycles. These reactions could be a key step in multicomponent coupling and cycloaddition reactions to afford nitrogen-containing organic compounds.

Graphical abstract: Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

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Article information


Submitted
12 Feb 2015
Accepted
02 Apr 2015
First published
13 Apr 2015

This article is Open Access

Dalton Trans., 2015,44, 12060-12073
Article type
Perspective
Author version available

Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

M. Ohashi, Y. Hoshimoto and S. Ogoshi, Dalton Trans., 2015, 44, 12060
DOI: 10.1039/C5DT00640F

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