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Issue 11, 2015
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Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates

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Abstract

The 1,3-dipolar cycloaddition reactions of the electron deficient boron azide, (C6F5)2BN3 (1) with the electron-poor acetylenes RO2CC[triple bond, length as m-dash]CCO2R (R = Me, Et) afforded the new mono- and bis-1,2,3-triazole derivatives 5 and 6.

Graphical abstract: Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates

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Publication details

The article was received on 22 Jan 2015, accepted on 10 Feb 2015 and first published on 11 Feb 2015


Article type: Communication
DOI: 10.1039/C5DT00316D
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Citation: Dalton Trans., 2015,44, 5045-5048
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    Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates

    R. L. Melen and D. W. Stephan, Dalton Trans., 2015, 44, 5045
    DOI: 10.1039/C5DT00316D

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