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Issue 11, 2015
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Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

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Abstract

New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.

Graphical abstract: Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

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The article was received on 01 Dec 2014, accepted on 02 Jan 2015 and first published on 12 Jan 2015


Article type: Communication
DOI: 10.1039/C4DT03677H
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Citation: Dalton Trans., 2015,44, 5041-5044

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    Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

    S. Luaces, R. Macías, M. J. Artigas, F. J. Lahoz and L. A. Oro, Dalton Trans., 2015, 44, 5041
    DOI: 10.1039/C4DT03677H

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